JAMB Chemistry Past Questions & Answers - Page 423

2,111.

The electron configuration of \(_{22}X^{2+}\) ion is

A.

1s2 2s22p6 3s2 3p6 4s2 3d2

B.

1s2 2s22p6 3s2 3p6 4s2 3d1

C.

1s2 2s22p6 3s2 3p6

D.

1s2 2s22p6 3s2 3p6 3d2

Correct answer is D

\(_{22}X^{2+}\) has 22 electrons but has been ionized to 2+ by giving off 2 electrons. Hence, the ion \(_{22}X^{2+}\) has 20 electrons.

The electronic configuration = 1s\(^2\) 2s\(^2\) 2p\(^6\) 3s\(^2\) 3p\(^6\) 3d\(^2\) 

the general trend for the first-row transition metals is that they lose electrons from their 4s orbitals first before 3d when forming ions. but this is not true for chromium and copper due to stability related to half-filled or completely-filled 3d orbitals

2,112.

Which of the following statement is correct about the periodic table?

A.

Elements in the same period have the same number of valency electron

B.

The valence electron of the elements in the same period increase progressively across the period

C.

Elements in the same group have the same number of electron shells

D.

The non-metallic properties of the elements tend to decrease across each period

Correct answer is B

The valence electron of the elements in the same period increase progressively across the period due to an increase in atomic number

2,113.

The fundamental difference between the three states of matter is the

A.

shape of their particles

B.

number of particles in each state

C.

shape of the container they occupy

D.

degree of movement of their particles

Correct answer is D

the fundamental difference between the three states of matter is their degree of movement, gaseous particles are very loosely packed hence they can move about easily. The particles of solids are closely packed so solids only make vibrational movement, while liquid particles can move past each other because their particles are not as closely packed as those of solids. 

2,114.

The partial pressure of oxygen in a sample of air is 452 mm Hg and the total pressure is 780 mm Hg. What is the mole fraction of oxygen?

A.

0.203

B.

0.579

C.

2.030

D.

5.790

Correct answer is B

Mole fraction = \(\frac{\text{Partial pressure of component}}{\text{Total pressure of compound}}\)

= \(\frac{452}{780}\)

= 0.579

2,115.

The ratio of the initial to final pressure of a given mass of gas is 1:1.5. Calculate the final volume of the gas if the initial volume was 300 cm3 at the same temperature

A.

120 cm3

B.

200 cm3

C.

450 cm3

D.

750 cm3

Correct answer is B

From P1V1 = P2V2
1 * V1 = 1.5 * V2
((1 * 300)/1.5) = V2
∴ V2 = 200 cm3